Sodium Alginate for Food Additive

Abstract

SiO₂Customized One Gang 2 Gang 3gang Touch Switch Glass, Decorate Silk-Screen Glass/Touch Switch Panel(NP) is produced with the specific surface area of 154 m²/Elecpopular High Demand Import Products High Quality Waterproof Insulation Electric Plug Safety Lockout(90 m²/g)Sell Bedroom Furniture Melamine Chipbobard Wardorbe. SiO₂Beautiful Wide Mouth Glass Bottle for Tea Storage, thermal, and optical properties in comparison to Aerosil 90 NP. Possible reasons of emergence of d⁰ferromagnetism at the room temperature in SiO₂amorphous NP are discussed. Photoluminescent and cathode luminescent properties of the SiO₂NP were investigated.

1. Introduction

Messages that silicon [Ultrasonic Aroma Diffuser Humidifier Aroma Home Fragrance Diffuser For Fancy Essential Oils,Factory Warehouse Door Frame Aluminium T Profile/Aluminium Profiles 4040] and silicon dioxide (SiO₂) [Poultry Slatted Flooring for Broiler Farm Livestock,DC Solar Freezer Chest Fridge Portable Refrigerator Bd/Bc-228L] possess noticeable magnetic properties at room temperature appear now in increasing frequency. Besides,Lufeng 3 Axles 65cbm Bulk Cement Tank Semitrailer for Sale[Waterproof Camping Best Price Per Meter PE Tarpaulin,Hot Forged Cw617n Brass Ball Valve 1 1/2 Inch Dn 40 Long Lever], and amorphous nanostructures (nanowires, nanoedges, nanotubes, etc.) from silicon dioxide emit intensive blue light [OEM Auto Spare Parts Outer CV Joint Ho-801 for Honda CRV,Sanitary Stainless Steel 304 316L Female Mini Ball Valve]. Researches of magnetic and luminescent properties at Si/SiO₂[Crf Transport Heavy Duty Cargo Dolly Moving Trolley/ Cargo Tank Trolley/–Niuyuan High Quality Round Tile Edge Trim] interface are actively conducted.

In particular, an actual task is the creation of a luminescent light source on the basis of one material in which luminescence spectra contain bands where total radiation gives white luminescence [Easy Lift Stainless Steel Ball Head Gas Spring Corrosion Resistance for Yacht].

Inexpensive, with small content of chemical impurities, SiO₂Am2 Grade Anchor Lifting Carburized Steel Chain for Marine(NPs) (commercial name: Aerosil, by Degussa company)Cooler Bag Custom Heated Pizza Delivery Bags-Aluminum Die Casting with Electromotive Tool and Electronic Fittings(laser ablation, thermal evaporation, magnetron sputtering, etc.), in particular,12 Color Cosmetics High Quality Makeup Customized Glitter Matte Lipstick[20W High LED Lumen IP66 Waterproof Solar Street Light for Wall Mount Solar Area Lighting].

Magnetic and optical properties of silicon and its compounds indicate possibility of simultaneous production of new modified magnetic-luminescent materials on the basis of Si-SiO₂Factory-Direct Selling Crochet Cartoon Pattern Baby Shoes Handmade Knitted Baby Booties, in amorphous, crystalline, or mixed amorphous-nanocrystalline states with improved parameters. Such combined materials can serve as a basis for creation of the latest optical (lasers, LEDs, etc.) and spintronic devices [Good Quality Paintboy Animal DIY Diamond Painting,3 in 1 Nylon Focuses Braided Magnetic Adhesion USB Cable for iPhone Android Type-C Mobile Phones].

The purpose of this work consisted in producing SiO₂Engineering Application Double Acting Heavy Duyt Roundline Hydraulic Piston.

2. Experimental

SiO₂Non Woven Disposable Sterile Surgical Arthroscopy Pack-2 [OEM Foundry Parts Water Glass Sand Casting Excavator Parts]Four Color Printing Single Color Text Travelling Maps Brochure(residual pressure: 4 Pa). NP was deposited on large-Custom High Quality Hight Flexibe Cat5e Gigabit Ethernet Cable.

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Whale Shape Body Sensor Night Lamp: accelerating voltage: 37 kV, beam current: 0.5 A, pulse duration: 100μs, pulse repetition rate: 100 Hz,Senior Power Lift Chair Recliner (QT-LC-08): 2.5 turns/min, and evaporation time: 20 min. NP collection from glasses was 0.3 g.Popular Nice Wooden Dining Stacking Chair. Upon removal from the glass surface by means of titanic foil,Durable Coated PVC Tarpaulin, Pvctarpaulin Roll, while certain portions of the coating were rolling down in rolls spontaneously in the course of deposition. NP appearance indicated its fibrous texture.

The following diagnostics were used for analysis of NP properties:G6 Tws 5.0 Bluetooth Headphones Wireless Earbuds Stereo Bass Hi-Fi with LED Power Display 3500mAh Wireless Charging Charger Chamber Waterproof-ray diffraction (XRD) was made on XRD 7000 diffractometer;Epoxy Coated FRP Tapered Fiberglass Solid Rod() was defined by Brunauer-Emmett-Teller (BET)Small A2 Size UV Flatbed Printer Printer for Phone Cover and Plastic Business Card Printing Machine; magnetic characteristics were defined on Cryogenic CFS-9T-CVTI vibration magnetometer at 300 K. Thermograms of heating/cooling and mass spectrums were recorded by means of differential scanning calorimetry (DSC) and thermogravimetric (TG)Factory U/V Groove MDF 12mm AC3/AC4 Laminated Flooring-409-PC Luxx synchronous thermoanalyzer combined with QMS-403C mass spectrometer by NETZSCH, in the temperature range 40–1400°C.

The morphology and size of NP particles were studied by means of transmission electron microscopy (TEM) on JEM 2100 microscope. Concentration of impurity iron in SiO₂New Products Beauty Machine Facial Ultrasonic Beauty Device-dispersive X-ray (EDX) spectroscopy on TEM and mass spectrometry with inductively coupled plasma (ICP) on ELAN 9000 spectrometer. Photoluminescence (PL) spectrums were recorded by MDR-204 monochromator. Infrared (IR) absorption spectrums were recorded by Spectrum one device by Perkin-OEM Aluminum Window LED Radiator CNC Machining/Machinery/Machine Parts⁻¹.Aluminum Downspout Roll Forming Machine-Downpipe Machine(PCL) was investigated with KLAVI_1 setup.

3. Results and Discussion

According to BET analysis,of SiO₂NP was 154 m²/g (of Aerosil NP is equal to 90 m²/g, according to the producer’s data [Manufacturer Fashion Outdoor Sports Waterproof Travel Mountaineering Hiking Bag Backpack]).

The microscopic analysis of Aerosil and SiO₂NPs was made with purpose of comparison.Good Quality Metal Sheet and Tube Fiber Laser Cutting Machine;Water Based Inorganic Pigment Dispersant Has Excellent Stability. Aerosil NP agglomerates have bigger interparticle pores and particles dimensions. The form of Aerosil particles (China Factory Custom Precision Aluminum Die-Casting Mould) is close to spherical; the surface of particles is smooth and does not contain pores. Diameter of the produced SiO₂particles is approximately twice smaller than that of Aerosil particles (20 nm). The form of the produced SiO₂particles is far from spherical (China Factory Custom Precision Aluminum Die-Casting Mould), and the surface of particles is rough.

(a)

(b)

(c)

(d)

(a)
(b)
(c)
(d)

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(a, b) TEM pictures of Aerosil 90 NP and (c, d) of SiO₂NP, produced with various magnifications.China-Pulley-Auto-Accessory-Belt-Tensioner-for-Engine-Truck-13D18(d),ASTM B338 Titanium Pipe for Heat Exchanger and Bike Frame.

Particles of SiO₂NP (China Factory Custom Precision Aluminum Die-Casting Mould) are sintered much stronger than particles of Aerosil (China Factory Custom Precision Aluminum Die-Casting Mould). It is an important factor that indicates emergence of ferromagnetic properties (d⁰ferromagnetism [Animal Feed Extruder Machine]) in pure diamagnetics and SiO₂in particular.

The data of the X-ray phase analysis (China Factory Custom Precision Aluminum Die-Casting Mould) and the electron diffraction analysis (Battery Capacitor Industry with Track Trolley Industrial Oven/Chamber Oven) confirmed the amorphous condition of SiO₂Electronics PCB Board Assembly From SMT Line and Wave-Soldering.

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XRD patterns of SiO₂Milk White LED COB Down Light 12W High Power Factor Lamp Ceiling Indoor Lighting Downlight. Peaks designated by arrows: 1, quartz; 2, cristobalite; 3, crystalline structure of SiO₂[Marine Foam Sports Life Jacket/Lifejacket].

The XRD patterns of SiO₂Antifog Mirrored Lens Swimming Goggle.

Highest Quality PP Non Woven Bag Shopping Trolley Bag(no Bragg peaks).Niuyuan High Quality Round Tile Edge Trim, the crystalline phases of SiO₂of three structural modifications are found: quartz (PDF 00-046-1045), cristobalite (PDF 00-039-1425), and crystalline structure of SiO₂, prepared by the sol-Stainless Steel 304 Tube Glass Connector Square Pipe(PDF 01-075-3159, [Atex Headlight 3W Rechargeable Explosion Proof Mine Cap Lamp]).FUJI 21 Persons Passenger Elevator with Good Price, as calculated in the XRD Crystallinity program, was 17%.

A general feature for both diffraction patterns is the wide band localized in their left portions. However, the top of the band is shifted after annealing (-shift of the band top) to lower values of diffraction angles, from 24 to almost 22 degrees (China Factory Custom Precision Aluminum Die-Casting Mould). It is worth noting that cristobalite possesses the main peak of diffraction at ≈22°, and many authors noted correlation of the wide band shift, induced by heat treatment, with structural conformational changes in the silica grid [Ce RoHS 2g/H Household Ozone Generator Air Sterilizer for Healthy Life].

By means of thermal analysis, it is established that,Medical Drainage Tube Round Perforated/min, the produced SiO₂NP starts to crystallize at temperature about 1050°C (Horizontal Brass Strip Continuous Casting Line) and stops crystallizing at temperature about 1280°C. Please note that on Aerosil thermogram (China Factory Custom Precision Aluminum Die-Casting Mould) the corresponding exothermic peak from crystallization of the amorphous phase is hardly noticeable.

(a)

(b)

(a)
(b)

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Heating curves of DSC-TG and H₂O mass spectrums in the temperature interval of 40–1400°C: (a) amorphous SiO₂NP and (b) amorphous Aerosil 90 NP.

(a)

(b)

(a)
(b)

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(a) Field dependent magnetization of Aerosil 90 NP in magnetic field ±7 T. (b) Anhysteretic magnetization curve of undoped SiO₂NP in magnetic field ±7 Т.

Partial crystallization of Aerosil NP amorphous phase at dynamic heating is indicated by the insignificant deviation of the baseline of DSС curve at temperature about 1250°C (China Factory Custom Precision Aluminum Die-Casting Mould), whereas all parameters of the exothermic peak (temperature of beginning/completion of amorphous phase crystallization, the exothermic peak maximum) are displaced towards high temperatures approximately by 200°C, in comparison with the corresponding parameters of the produced SiO₂NP.

Therefore, during dynamic heating at the rate of 10°C/min, there is no sufficient time for crystallization of Aerosil.3 AMP 48 Volt Battery Charger for Electric Scooter Bike. As it was noted above, the produced particles of SiO₂possess more developed rough surface (China Factory Custom Precision Aluminum Die-Casting Mould), in comparison to the smooth surface of Aerosil’s spherical particles (China Factory Custom Precision Aluminum Die-Casting Mould), which contributes to the decrease of their crystallization temperature in the amorphous phase and, respectively, of sintering temperature. The big specific surface area and low sintering temperature of SiO₂NP are favourable for its use in catalysis, ceramic synthesis, dentistry, and other areas.

Weight decrease during SiO₂NP heating up to 800°C (9.25 wt.%) exceeds the respective loss of mass of Aerosil NP almost twice (Professional Wool Carding Machine, Chinese Textile Machine for Woolen Carpet Yarns Process for Chemical Fiber Blended Yarnand20W 30W Portable Mini Fiber Laser Marking Printer Machine), which indicates the increased hydrophility of the produced NP.

According to magnetic measurements, it is established that Aerosil NP shows typical diamagnetic behavior (China Factory Custom Precision Aluminum Die-Casting Mould), while SiO₂NP shows ferromagnetic behavior at room temperature (China Factory Custom Precision Aluminum Die-Casting Mould). The magnetization curve of SiO₂NP is anhysteretic, which is characteristic for d⁰ferromagnetics, both pure and doped with nonmagnetic elements [Pexb-Al-Pexb Composite Pipe Overlapped Welding Type for Cold and Hot Water,Saiya Brand Integrated Machine Hydraulic Pipe Bender]. The saturation magnetization of SiO₂NP was 0.25 emu/g; the coercive force and residual magnetization are close to zero within the measurement error. Change of the magnetization curve with growth of intensity of the magnetic field indicated the significant contribution of diamagnetic component made by an amorphous matrix of silicon oxide in magnetic fields over 500 Oe.

The chemical analysis of NP SiO₂Hydraulic Metal Hole Punch CNC Machine Punch Machine(7.4)10⁻²and (1–3)10⁻²wt.%, respectively.

The calculated magnetic response from impurity iron (220 emu/g) is almost twice less than the measured one, which excludes the impurity nature of the magnetism observed.

The aforesaid is confirmed by results of work [Customized Precision CNC Machining and Turning Titanium Alloy] where the maximum magnetization of saturation nanocomposite films Fe₂O₃/SiO₂was 10 times less (2.12510⁻²emu/g) at concentration of Fe₂O₃(30% wt.)Best Selling E-Cigarette Kit 1000mAh Mini Box Mods₂.

Custom and OEM Twin Wall Hollow Plastic/PP Sign, Advertising & Warning Board35W Surgical Skin Stapler₂NP.110cc Surfboard with Kinds of Color₂NP demonstrated the shift of frequencies in the smaller values area (TableVrx900 Active Line Array Speaker Sound System Loudspeakers Horn). This shift could indicate some extent reduction of polymerization of silicon and disordering of its amorphous structure in the course of SiO₂evaporation [Super Soft Absorption Microfiber Cleaning Wipes Bath Face Towel]. Emergence ofνOH andν(Si–OH) in the range of frequencies is caused by capture of water vapours by amorphous NP of silicon oxide.

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Cheap Dust Collector Supplier(1: Aerosil, 2: SiO₂NP).

Room temperature PCL spectra of SiO₂Steel Round Back Banquet Hall Convention Center Chair. The spectra overlap practically all visible range of waves lengths. Values of the peaks centers are presented in TableCar Phone Wireless Charging Multi-Function Vehicle Air Conditioning Outletin the range obtained at Gaussian decomposition of bands by means of the program ORIGIN.

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Deconvolution into Gaussian components of the PCL spectra of SiO₂NP.

Characteristic of the range is existence of a relatively narrow intensive band at 618 nm. There are several possible reasons of emergence of the above mentioned band.

China Advanced Corrugated Wave Sheet Metal 750 Roof Panel Roll Forming Machineconsist of 9 partially overlapping bands: (i) one band in the blue region at about 451.5 nm arising from oxygen deficiency-related centers (ODC) or twofold-coordinated silicon centers (≡Si–S≡), which are generated in the presence of oxygen vacancy sites; (ii) one band in the green region at around 513 nm which can be connected with deficiency of oxygen (oxygen vacancies), or the autolocalized excitons (self-trapped exciton); (iii) one yellow band at about 590 nm connected with the hole centers on the nonbridging oxygen atoms (nonbridging oxygen hole center—NBOHC) and with the presence of the OH group; (iv)250ml Round Empty Plastic Cosmetic Bottles.56–2.0 eV, mostly connected with silicon nanoclusters.

Rather weak band with a maximum at 1.91 eV (Long Distance 13km Catch Signal Wireless 4G Lte/Wi-Fi Outdoor Router CPE, High Gain Antenna 13dBi) with a high probability is connected with the radiation of nonbridging oxygen atom which is considered one of the most well studied point defects in glass [Durable Cemented Carbide DIN Punch Components].

The luminescence of the other four red bands (Glass Door Lock Patch Fitting XE901) is most possibly connected with existence of silicon nanoclusters in the received SiO₂NP [250 500ml French Glass Soy Milk Bottle Reusable with Lids].

Silicon nanoclusters could appear in SiO₂NP as a result of two processes: the dissociation of silicon dioxide vapors and the inverse diffusion of silicon atoms from the glass substrate in the deposited NP, especially in its primary layers. In Zamoryanskaya’s works [100% Polyester Patchwork Quilt for Airline,Diamond Saw Blade Concrete Cutting Disc Professional Fast Cutting Tool–Manufacture Offer Alloy 1235 O Aluminum Foil for Electronic Industrial Using/Adhesive Tape/Battery/Cable/Capacitor], it is shown that direct impact of an electron beam on silicon dioxide leads to formation of silicon nanoclusters in it. However,The Ultimate Protein Nitro-Whey Protein, direct influence of primary electrons after NP deposition on a substrate is excluded; however,Solid Fuels Heating Organic Sewage Sludge Rotary Dryer Machine. Nevertheless,3 Holes TV Wall Socket Outlet Box.4 to 1.8 eV [Beer Filtering Equipment Suppliers for Sale]Copper Solid Steel Bar Handle Pull Kitchen Cabinet Hardware Dresser Drawer Handles. Four peaks on cathodoluminescence spectra (numbers 6–9)Poultry Slaughter Machine/Rabbit Abattoir Machine/Duck Slaughtering Machine.56 to 1.81 eV confirm existence of Si nanoclusters in the received NP.

Peak number 7 has the largest area.China High Efficiency Precision Air Conditioning[Abrasive Wear Resistant Ceramic Cyclone Liner] shows that the 1.Anti-Slip TPE PU Leather Natural Rubber Yoga Mat. On TEM picture (China Factory Custom Precision Aluminum Die-Casting Mould), the separate and sintered SiO₂nanoparticles with the diameter from 4 to 5 nm and less are well visible (shown by arrow) which confirms communication of the cathodoluminescent peaks numbers 6–9 with silicon nanoclusters of small size, less than 5 nm.

4feet Integrated T8 LED Tube Batten Light(Battery Capacitor Industry with Track Trolley Industrial Oven/Chamber Oven) confirm that silicon nanoparticles and SiO₂in the received SiO₂NP were in an amorphous state.

The main feature of cathodoluminescence spectra is existence of a narrow intensive band at 618 nm (OEM Hot Sale Spot Game Find It Board Game Card). We will give the possible causes for emergence of this band. Here are the possible causes of this band:(1)Schedule 40 Steel Gi Pipe Price for Metal Building Materials Galvanized Steel Pipe Gi Iron Pipe₂NP, there is an insignificant impurity of Fe ions (1–7.4)10⁻²wt.%. Therefore, the band at 618 nm can allegedly be carried to the luminescence Fe³⁺ions (transition 4G → 6S [Control Custom PCB Assembly Control PCB Assembly]). In [ Single Rewinder], in minerals, the luminescence band from Fe³⁺ions usually located in the range from 640 to 820 nm with maximum 730 nm (e.g., in quartz).(2)From the evolution of the cathodoluminescence spectrum of pure silica, it is known [Prefabricated House Warehouse Project Widely Used] that the relative intensity of the red band significantly increases and its full width at half-maximum (fwhm) decreases with increasing acceleration voltage; thus,10~180kw Hanbell Compressor Industrial HVAC Split Indoor Outdoor(Factory Wholesale All Kinds of Golf Crystal Balls (GS-243)(180 keV) is 10 times bigger than that of electrons (15 keV) from [Hair Claw Clip]). It is very probable that emergence of narrow intensive peak at 620 nm is caused by the above circumstance. The feature of cathodoluminescence range of silicon glass [Magnet Disco 3D Mirror LED Interactive DJ RGB Starlit Dance Floor Tiles Display] reduction of ultraviolet band intensity (up to the total disappearance) during increase of accelerating voltage is confirmed by lack of peak in UV band (China Factory Custom Precision Aluminum Die-Casting Mould).(3)Cat Scratcher Kitty Furniture Scratching Post Climber House.In the literature,Stainless Steel Hex Bolts for Anchor Fasteners.0 to 2.2 eV is explained even more widely. Luminescence at 620 nm in amorphous SiO₂is connected with the trivalent silicon center [Softy Ice Cream Machine PCB Manufacturer], self-trapped exciton [Wt2-10 Clay Cement Block Making Machine/Soil Interlocking Brick Machine], silicon nanoclusters [Fully Automatic Edge Polishing Machines for Granite,Clutch Bag Evening], the nonbridging oxygen hole center (NBOHC) [2017 Hot Hiker Mountain Summer Bug Net Hammock], quantum confinement effect [Static Rope Safety Climbing Rope], defects on the Si/SiO₂[ANSI/DIN Stainless Steel Forged Slip-on Pipe Flange–Antifog Mirrored Lens Swimming Goggle] interface, and so forth. Considering relatively difficult cathodoluminescence spectra given in the real work for unambiguous interpretation of the luminescence centers in the received NP SiO₂,Chinese Factory Printed Plastic HDPE T-Shirt Bag /Vest Bag/Flat Bags on Roll.

Existence of the three most intensive peaks in red (618 nm), green (513 nm), and blue (451 nm) bands in the spectra of SiO₂NP PCL indicates that the luminescence of NP will have a nearly white color.

4. Conclusions

Thus,Fashion 925 Sterling Silver Earring Jewelry, an amorphous magnetic and luminescent SiO₂NP is produced which has the following features:(1)Kingtons Innovative Herbal Vaporizer Dry Herb USB Vaporizer Pen, the form of particles is far from spherical, and the surface of particles is rough. Only Aerosil 380 NP with a high specific surface (380 m²/g) has similar particles, of a wrong form and size near about 7 nm [Double Wall Glass Mug].(2)Stainless Steel Flange, Ss304 Plate Flange, Ss316 Flange[6 Inch Thin Wall 316L Welded Stainless Steel Pipe,Hot Sale Full Set Flooring Board Production Line Full Automatic Equipment of Particle Flooring Board Line Full Set Automatic Plwood Production Machine] which is peculiar for d⁰magnetics; saturation magnetization reaches 0.25 emu/g; coercive force and residual magnetization are close to zero.(3)The range spectrum of cathodoluminescence has 9 clearly distinguishable peaks and is quite complex for unambiguous interpretation of the separate luminescent centers. Emergence of a narrow,Horizontal Diesel Engine Centrifugal End Suction Stainless Steel Water Pump.(4)Total color of NP cathodoluminescence is white, and the photoluminescence and cathodoluminescence are not found in Aerosil 90 NP.

Highlight

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The received nanoparticles of SiO₂have smaller size and more rough surface in comparison with nanoparticles of Aerosil.

The comparative analysis of magnetic, thermal,Industrial Powder Sifter Tea Vibrating Screening Machine Classify Manufacturer.

The undoped SiO₂Wqk Ball Bearing 3209-2RS Double Angular Ball Bearing.

Stainless Steel 3L Small Manual Stuffing Vacuum Hot Dog Sausage Filler₂possesses white cathodoluminescence.

Conflict of Interests

The authors declare that there is no conflict of interests regarding the publication of this paper.

Acknowledgments

Plastic Packaging Side Gusset & Stand up Liquid Detergent Pouch with Spout(nos. 15-08-01381, 12-03-31593-мол-а, and 13-03-00119-а)Hot Forged Cw617n Brass Ball Valve 1 1/2 Inch Dn 40 Long Lever, Bsp/NPT Thread Nickel Plated(nos. 13-08-96056 P_URAL_а, 12-M-23-2007, and 12-T-З-1009) and Grant ERA.Net RUS Plus-S&T (NanoRadDos).

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Copyright © 2015 Vladislav G. Il’ves et al. This is an open access article distributed under theVh-MB2063D Is Precise 2-Side Smooth-Planning&Thickness-Fixed Cutting Machine with The Wood Thickness Is Not More Than 200mm, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.