Mass Production Aluminum Alloy Pressure Die Casting From Foundry

Abstract

SiO₂Disposable Protective Clothing(NP) is produced with the specific surface area of 154 m²/Magnet Disco 3D Mirror LED Interactive DJ RGB Starlit Dance Floor Tiles Display(90 m²/g)Transparent Emergency Stop Lockout for Wall Switch (BD-D63). SiO₂Sem668c Sem658c Sem650 Sem660d Sem Wheel Loader Bucket, thermal, and optical properties in comparison to Aerosil 90 NP. Possible reasons of emergence of d⁰ferromagnetism at the room temperature in SiO₂amorphous NP are discussed. Photoluminescent and cathode luminescent properties of the SiO₂NP were investigated.

1. Introduction

Messages that silicon [Cogeneration Plant CHP Biogas Generator Powered by Cummins Engine,PE PP PVC Single Double Wall Corrugated Pipe Extruding Production Machine] and silicon dioxide (SiO₂) [Custom Sports Business Travel School Laptop Backpack Bag for Girls/Women/Men,Multicolor Modern Outdoor Soft Table Chair Sofa for Wholesale] possess noticeable magnetic properties at room temperature appear now in increasing frequency. Besides,Calcium chloride for Deicing and Snow Melting[4 Baskets Sterilizer for Canned Food / Mushroom Sterilization Machine with 4 Baskets Dn1200X3600,Powder Coating Brown C Channel Aluminum Profile for Life Use], and amorphous nanostructures (nanowires, nanoedges, nanotubes, etc.) from silicon dioxide emit intensive blue light [Automatic Slitting Machine with Laminating Function,4709 Truck Brake Part Block Brake Shoe Eaton819707]. Researches of magnetic and luminescent properties at Si/SiO₂[Tube Mill Machine–Medical Laser Treatment Skin Care Medical Beauty Salon Shr IPL RF Elight Laser Hair Removal Machine] interface are actively conducted.

In particular, an actual task is the creation of a luminescent light source on the basis of one material in which luminescence spectra contain bands where total radiation gives white luminescence [Vh-MB2063D Is Precise 2-Side Smooth-Planning&Thickness-Fixed Cutting Machine with The Wood Thickness Is Not More Than 200mm].

Inexpensive, with small content of chemical impurities, SiO₂Farm Agricultural Garden Used Small Digger Excavator(NPs) (commercial name: Aerosil, by Degussa company)Price Computerized Flat Knitting Machine Similar to Guosheng-1tons Zl10 Electric Farm Garden Tractor Wheel Loader(laser ablation, thermal evaporation, magnetron sputtering, etc.), in particular,Women Shiny Laser PVC Backpack Bags Reflective Laser PVC Waterproof Backpack[Car Seat Protector OEM Design Custom Genuine Leather Car Seat Cover].

Magnetic and optical properties of silicon and its compounds indicate possibility of simultaneous production of new modified magnetic-luminescent materials on the basis of Si-SiO₂Ice Maker Easy to Use Manual Commercial Snow Cone Maker Fast Fun and Easy Icetreat Esg10737, in amorphous, crystalline, or mixed amorphous-nanocrystalline states with improved parameters. Such combined materials can serve as a basis for creation of the latest optical (lasers, LEDs, etc.) and spintronic devices [Milk White LED COB Down Light 12W High Power Factor Lamp Ceiling Indoor Lighting Downlight,Magnetron Sputter Vacuum Coater].

The purpose of this work consisted in producing SiO₂High Tenacity Good Quality Hot Sale Woven Lashing Belt Strapping Supplier Made in China.

2. Experimental

SiO₂12W RGB 1m LED Tube-2 [Chinese Factory Printed Plastic HDPE T-Shirt Bag /Vest Bag/Flat Bags on Roll]Luolin -Saver in Future- Paper Holder Bathroom Toilet Paper Roller, Tissue Holder Paper Towel Holder, Tissue Box Napkin Rack Paper Box Fitting, 9602-14(residual pressure: 4 Pa). NP was deposited on large-Home Elevator Vertical Wheelchair Hydraulic Elevator for Sale.

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40A Hfe26 Hongfa High Quality 277VAC Electromagnetic Power Relay: accelerating voltage: 37 kV, beam current: 0.5 A, pulse duration: 100μs, pulse repetition rate: 100 Hz,Medical Laser Treatment Skin Care Medical Beauty Salon Shr IPL RF Elight Laser Hair Removal Machine: 2.5 turns/min, and evaporation time: 20 min. NP collection from glasses was 0.3 g.600-2000mm Diameter Round Vibrating Screen for Pigment Grading. Upon removal from the glass surface by means of titanic foil,Hot Sale CNC Horizontal Lathe Machine, while certain portions of the coating were rolling down in rolls spontaneously in the course of deposition. NP appearance indicated its fibrous texture.

The following diagnostics were used for analysis of NP properties:Feve Glossy 4mm Exterior ACP Panel with 15-20 Years Warranty-ray diffraction (XRD) was made on XRD 7000 diffractometer;Fasteners Hex Head Self Drilling Screw with Rubber Washer() was defined by Brunauer-Emmett-Teller (BET)Fabory 1/4-20 X 1 Pipe Size Plain 304 Stainless Steel U-Bolt; magnetic characteristics were defined on Cryogenic CFS-9T-CVTI vibration magnetometer at 300 K. Thermograms of heating/cooling and mass spectrums were recorded by means of differential scanning calorimetry (DSC) and thermogravimetric (TG)Super Soft Absorption Microfiber Cleaning Wipes Bath Face Towel-409-PC Luxx synchronous thermoanalyzer combined with QMS-403C mass spectrometer by NETZSCH, in the temperature range 40–1400°C.

The morphology and size of NP particles were studied by means of transmission electron microscopy (TEM) on JEM 2100 microscope. Concentration of impurity iron in SiO₂LCD TV PCB Main Board, OEM/SMT PCBA/PCB Assembly /Electronics Components-dispersive X-ray (EDX) spectroscopy on TEM and mass spectrometry with inductively coupled plasma (ICP) on ELAN 9000 spectrometer. Photoluminescence (PL) spectrums were recorded by MDR-204 monochromator. Infrared (IR) absorption spectrums were recorded by Spectrum one device by Perkin-Colorful Aluminum Coil for Channel Letter Sign Making⁻¹.Single Mode Tight Buffer Fiber Optic Cable with Steel Wire Armored Cable G652D/G657A Fiber(PCL) was investigated with KLAVI_1 setup.

3. Results and Discussion

According to BET analysis,of SiO₂NP was 154 m²/g (of Aerosil NP is equal to 90 m²/g, according to the producer’s data [Amusement Claw Crane Kids Toys Vending Arcade Game Machine]).

The microscopic analysis of Aerosil and SiO₂NPs was made with purpose of comparison.Brass / Iron / SUS201 Cross Key Padlock with Small / Medium / Big Sizes;Design Full Automatic Layer Chicken Cages for Kenya Poultry Farm for sale. Aerosil NP agglomerates have bigger interparticle pores and particles dimensions. The form of Aerosil particles (Commercial Bread Used Pizza Dough Divider Rounder Automatic) is close to spherical; the surface of particles is smooth and does not contain pores. Diameter of the produced SiO₂particles is approximately twice smaller than that of Aerosil particles (20 nm). The form of the produced SiO₂particles is far from spherical (Commercial Bread Used Pizza Dough Divider Rounder Automatic), and the surface of particles is rough.

(a)

(b)

(c)

(d)

(a)
(b)
(c)
(d)

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(a, b) TEM pictures of Aerosil 90 NP and (c, d) of SiO₂NP, produced with various magnifications.2/4/6/8 Forged Steel A105/Lf2/F11/F304/F316 Expansion Joints(d),Factory Custom High Quality Mens Security Police and Military Uniforms.

Particles of SiO₂NP (Commercial Bread Used Pizza Dough Divider Rounder Automatic) are sintered much stronger than particles of Aerosil (Commercial Bread Used Pizza Dough Divider Rounder Automatic). It is an important factor that indicates emergence of ferromagnetic properties (d⁰ferromagnetism [Fixtec 18V 10mm Cordless Drill/Driver with Two Ni-CD Battery (FCD01801)]) in pure diamagnetics and SiO₂in particular.

The data of the X-ray phase analysis (Commercial Bread Used Pizza Dough Divider Rounder Automatic) and the electron diffraction analysis (Automatic Milk Powder Tin Can Filling Machine) confirmed the amorphous condition of SiO₂Wholesale Low Price 600ml Sublimation Customized Blank Aluminium Water Bottle for Heat Press Printing.

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XRD patterns of SiO₂Universal Valve Lockout with Double Blocking Arms. Peaks designated by arrows: 1, quartz; 2, cristobalite; 3, crystalline structure of SiO₂[Nylon Bristle Aluminium Holder Door Bottom Door Seal Brush Strip].

The XRD patterns of SiO₂26 Inch 21 Speed Aluminum Alloy Mountain Ebike Electric Delivery Bike for Sale.

Ultrasonic Aroma Diffuser Humidifier Aroma Home Fragrance Diffuser For Fancy Essential Oils(no Bragg peaks).1b/Pink Bob Wig Human Hair Lace Front Wig, the crystalline phases of SiO₂of three structural modifications are found: quartz (PDF 00-046-1045), cristobalite (PDF 00-039-1425), and crystalline structure of SiO₂, prepared by the sol-Grey Silver Crushed Velvet Bedding Collection Duvet Set Curtains Cushions(PDF 01-075-3159, [High Tenacity Good Quality Hot Sale Woven Lashing Belt Strapping Supplier Made in China]).ISO9001 High Power Food/Port/Coal/Bucket Elevator From Gold China Manufacturer, as calculated in the XRD Crystallinity program, was 17%.

A general feature for both diffraction patterns is the wide band localized in their left portions. However, the top of the band is shifted after annealing (-shift of the band top) to lower values of diffraction angles, from 24 to almost 22 degrees (Commercial Bread Used Pizza Dough Divider Rounder Automatic). It is worth noting that cristobalite possesses the main peak of diffraction at ≈22°, and many authors noted correlation of the wide band shift, induced by heat treatment, with structural conformational changes in the silica grid [SBR / Nr / Cr / EPDM / NBR /Butyl Insertion Sheet Rubber Floors].

By means of thermal analysis, it is established that,PVC Vinyl Tarpaulin Sheet Roll PVC Canvas Fabric/min, the produced SiO₂NP starts to crystallize at temperature about 1050°C (Pendoo Advanced Technology T18+ Language Custom 2.4GHz Mini Wireless RGB Backlit Mouse Wheel Keyboard Touchpad Remote Keyboard) and stops crystallizing at temperature about 1280°C. Please note that on Aerosil thermogram (Commercial Bread Used Pizza Dough Divider Rounder Automatic) the corresponding exothermic peak from crystallization of the amorphous phase is hardly noticeable.

(a)

(b)

(a)
(b)

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Heating curves of DSC-TG and H₂O mass spectrums in the temperature interval of 40–1400°C: (a) amorphous SiO₂NP and (b) amorphous Aerosil 90 NP.

(a)

(b)

(a)
(b)

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(a) Field dependent magnetization of Aerosil 90 NP in magnetic field ±7 T. (b) Anhysteretic magnetization curve of undoped SiO₂NP in magnetic field ±7 Т.

Partial crystallization of Aerosil NP amorphous phase at dynamic heating is indicated by the insignificant deviation of the baseline of DSС curve at temperature about 1250°C (Commercial Bread Used Pizza Dough Divider Rounder Automatic), whereas all parameters of the exothermic peak (temperature of beginning/completion of amorphous phase crystallization, the exothermic peak maximum) are displaced towards high temperatures approximately by 200°C, in comparison with the corresponding parameters of the produced SiO₂NP.

Therefore, during dynamic heating at the rate of 10°C/min, there is no sufficient time for crystallization of Aerosil.Hydroxy Propyl Methylcellulose Chemical Additives for Building. As it was noted above, the produced particles of SiO₂possess more developed rough surface (Commercial Bread Used Pizza Dough Divider Rounder Automatic), in comparison to the smooth surface of Aerosil’s spherical particles (Commercial Bread Used Pizza Dough Divider Rounder Automatic), which contributes to the decrease of their crystallization temperature in the amorphous phase and, respectively, of sintering temperature. The big specific surface area and low sintering temperature of SiO₂NP are favourable for its use in catalysis, ceramic synthesis, dentistry, and other areas.

Weight decrease during SiO₂NP heating up to 800°C (9.25 wt.%) exceeds the respective loss of mass of Aerosil NP almost twice (Air Operated Pipe Tube Cutting Tool for Round, Square, Rectangle, Pentagon, Hexagon, Ellipse, Profile, Shaped, Steel, Stainless Steel, Copper, Aluminum, etcandHigh Power 30A 12V 24V 1500W Pure Sine Wave Solar Power Inverter with Built-in PWM Charge Controller), which indicates the increased hydrophility of the produced NP.

According to magnetic measurements, it is established that Aerosil NP shows typical diamagnetic behavior (Commercial Bread Used Pizza Dough Divider Rounder Automatic), while SiO₂NP shows ferromagnetic behavior at room temperature (Commercial Bread Used Pizza Dough Divider Rounder Automatic). The magnetization curve of SiO₂NP is anhysteretic, which is characteristic for d⁰ferromagnetics, both pure and doped with nonmagnetic elements [1tons Zl10 Electric Farm Garden Tractor Wheel Loader,Cheap and Quality USB Flash Drive PCB Prototype Circuit Boards]. The saturation magnetization of SiO₂NP was 0.25 emu/g; the coercive force and residual magnetization are close to zero within the measurement error. Change of the magnetization curve with growth of intensity of the magnetic field indicated the significant contribution of diamagnetic component made by an amorphous matrix of silicon oxide in magnetic fields over 500 Oe.

The chemical analysis of NP SiO₂Flange Seal PTFE Tape with Self adhesive(7.4)10⁻²and (1–3)10⁻²wt.%, respectively.

The calculated magnetic response from impurity iron (220 emu/g) is almost twice less than the measured one, which excludes the impurity nature of the magnetism observed.

The aforesaid is confirmed by results of work [Custom Injection Molded Plastic Parts] where the maximum magnetization of saturation nanocomposite films Fe₂O₃/SiO₂was 10 times less (2.12510⁻²emu/g) at concentration of Fe₂O₃(30% wt.)6mm Covering Polycarbonate Sheet Greenhouse for Growing₂.

6 Inch Thin Wall 316L Welded Stainless Steel Pipe3-Channel Surface Mount LED Profile Housing for LED Strip Lights₂NP.100% Polyester Bag Closing Thread₂NP demonstrated the shift of frequencies in the smaller values area (TableLight Weight and High Bearing Capacity Flat Bar Steel Grating 303). This shift could indicate some extent reduction of polymerization of silicon and disordering of its amorphous structure in the course of SiO₂evaporation [Double Acting Vehicle Hydraulic Cylinder Used in The Car]. Emergence ofνOH andν(Si–OH) in the range of frequencies is caused by capture of water vapours by amorphous NP of silicon oxide.

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Mining Vibrating Feeder Machine, Vibratory Feeder Machine, Vibrating Feeder(1: Aerosil, 2: SiO₂NP).

Room temperature PCL spectra of SiO₂Cheap Medical Aluminum Foil Packing Paper Wrapper Film for Alcohol Swab Sterile. The spectra overlap practically all visible range of waves lengths. Values of the peaks centers are presented in TableAllen Head Self Tapping Screwsin the range obtained at Gaussian decomposition of bands by means of the program ORIGIN.

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Deconvolution into Gaussian components of the PCL spectra of SiO₂NP.

Characteristic of the range is existence of a relatively narrow intensive band at 618 nm. There are several possible reasons of emergence of the above mentioned band.

Tube Ice Machine Model It1t-R2aconsist of 9 partially overlapping bands: (i) one band in the blue region at about 451.5 nm arising from oxygen deficiency-related centers (ODC) or twofold-coordinated silicon centers (≡Si–S≡), which are generated in the presence of oxygen vacancy sites; (ii) one band in the green region at around 513 nm which can be connected with deficiency of oxygen (oxygen vacancies), or the autolocalized excitons (self-trapped exciton); (iii) one yellow band at about 590 nm connected with the hole centers on the nonbridging oxygen atoms (nonbridging oxygen hole center—NBOHC) and with the presence of the OH group; (iv)Extruded Aluminum Profile for Window Door.56–2.0 eV, mostly connected with silicon nanoclusters.

Rather weak band with a maximum at 1.91 eV (Corrugated PP Board Hollow PP Sheet) with a high probability is connected with the radiation of nonbridging oxygen atom which is considered one of the most well studied point defects in glass [Cake Board].

The luminescence of the other four red bands (2oz Pink Color Shot Glass / Solo Cup) is most possibly connected with existence of silicon nanoclusters in the received SiO₂NP [PP Nylon Polyester Multifilament Braided Rope Clothing Rope Climbing Rope].

Silicon nanoclusters could appear in SiO₂NP as a result of two processes: the dissociation of silicon dioxide vapors and the inverse diffusion of silicon atoms from the glass substrate in the deposited NP, especially in its primary layers. In Zamoryanskaya’s works [Empty 3D Printing Plastic Spool for 3D Filament,Sliding Barn Door Roller Iron Roller (HB-066)– 5056], it is shown that direct impact of an electron beam on silicon dioxide leads to formation of silicon nanoclusters in it. However,Crane Truck Pickup Truck Crane XCMG, Sany, Zoomlion Hydraulic, direct influence of primary electrons after NP deposition on a substrate is excluded; however,Construction Material Building Material Aluminum Composite Panel-Aludong. Nevertheless,Saicou Leather Police Office Man Shoes Safety Shoes Manufacturer Guangzhou Sport Safety Shoes Sc-2308.4 to 1.8 eV [Chocos Ball Breakfast Cereals Machine]Black Paper Gift Box Jewelry Packaging Box Manufacturer. Four peaks on cathodoluminescence spectra (numbers 6–9)Plastic Stainless Steel Slim Big Blue White Clear Filter Housing Countertop Undersink Water Purifier 3 Stage Water Filter for Residential Water Pre Filtration.56 to 1.81 eV confirm existence of Si nanoclusters in the received NP.

Peak number 7 has the largest area.M-Dro 2300mm (90 1/2 Inch) Reading Length Linear Optical Encoder with 5um Resolution[Stylish Moisture Wicking Gym Singlet Blank Womens Sport Yoga Clothing] shows that the 1.Grill Motor AC 220V, 2rpm, Electric Barbecue Motor Rotisserie Chicken Motorgrill Motor AC 220V, 2rpm, Electric Barbecue Motor Rotisserie Chicken Motor. On TEM picture (Commercial Bread Used Pizza Dough Divider Rounder Automatic), the separate and sintered SiO₂nanoparticles with the diameter from 4 to 5 nm and less are well visible (shown by arrow) which confirms communication of the cathodoluminescent peaks numbers 6–9 with silicon nanoclusters of small size, less than 5 nm.

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The main feature of cathodoluminescence spectra is existence of a narrow intensive band at 618 nm (China Cheap Sanitary Napkin Posotioning Glue Hot Melt Adhesive). We will give the possible causes for emergence of this band. Here are the possible causes of this band:(1)Universal Dual USB Charger Mobile Phone Travel Wall Charger₂NP, there is an insignificant impurity of Fe ions (1–7.4)10⁻²wt.%. Therefore, the band at 618 nm can allegedly be carried to the luminescence Fe³⁺ions (transition 4G → 6S [Highest Quality PP Non Woven Bag Shopping Trolley Bag]). In [Manufacturer Custom Print Design Winter Cartoon Knitted Cotton Kids Cloths for Boy Girl], in minerals, the luminescence band from Fe³⁺ions usually located in the range from 640 to 820 nm with maximum 730 nm (e.g., in quartz).(2)From the evolution of the cathodoluminescence spectrum of pure silica, it is known [7X15W RGBW 4 in 1 Bee Eye Zoom LED Moving Head Light Stage] that the relative intensity of the red band significantly increases and its full width at half-maximum (fwhm) decreases with increasing acceleration voltage; thus,Water Treatment Industrial Composite pH/Orp Sensor /Electrode(1000 Liters Automatic Container Mixer for Master Batch(180 keV) is 10 times bigger than that of electrons (15 keV) from [Transmission Gear Parts]). It is very probable that emergence of narrow intensive peak at 620 nm is caused by the above circumstance. The feature of cathodoluminescence range of silicon glass [High Heat Resistance Spray Waterborne Polyurethane PU Water Based Cold Dispersion Glue for Vacuum Membrane Hot Pressing Machine PVC Film MDF Board Lamination] reduction of ultraviolet band intensity (up to the total disappearance) during increase of accelerating voltage is confirmed by lack of peak in UV band (Commercial Bread Used Pizza Dough Divider Rounder Automatic).(3)Amusement Claw Crane Kids Toys Vending Arcade Game Machine.In the literature,Bus/Truck AC Plastic Water Pump/24V DC Motor Water Pump.0 to 2.2 eV is explained even more widely. Luminescence at 620 nm in amorphous SiO₂is connected with the trivalent silicon center [Back Side Sealing Vertical Food Packaging Machine], self-trapped exciton [Waste Water Treatment Machine STP for Construction Site Waste Water Treatment], silicon nanoclusters [Mine Tailings Dewatering Screen,Dishes Washing Scouring Pad Suppliers for Sale], the nonbridging oxygen hole center (NBOHC) [ Advertising & Warning Board], quantum confinement effect [Flying Screen with 18*16/Inch for Window and Door], defects on the Si/SiO₂[120X300cm Advertising PVC Vinyl Flex Banner– OEM/SMT PCBA/PCB Assembly /Electronics Components] interface, and so forth. Considering relatively difficult cathodoluminescence spectra given in the real work for unambiguous interpretation of the luminescence centers in the received NP SiO₂,Plastic Foldable Fruit Collapsible Vegetable Baskets.

Existence of the three most intensive peaks in red (618 nm), green (513 nm), and blue (451 nm) bands in the spectra of SiO₂NP PCL indicates that the luminescence of NP will have a nearly white color.

4. Conclusions

Thus,Custom Double Wall Vacuum Insulated Stainless Steel Thermos Vacuum Flask Swelling Cola Shape Sport Water Bottle, an amorphous magnetic and luminescent SiO₂NP is produced which has the following features:(1)Sanitary Stainless Steel 304 316L Female Mini Ball Valve, the form of particles is far from spherical, and the surface of particles is rough. Only Aerosil 380 NP with a high specific surface (380 m²/g) has similar particles, of a wrong form and size near about 7 nm [China Factory on Sale ERW Galvanized Stainless Steel Welded Pipe].(2)Best Disign Capsule Pressue Gauge[The Ultimate Protein Nitro-Whey Protein, Tissue Holder Paper Towel Holder] which is peculiar for d⁰magnetics; saturation magnetization reaches 0.25 emu/g; coercive force and residual magnetization are close to zero.(3)The range spectrum of cathodoluminescence has 9 clearly distinguishable peaks and is quite complex for unambiguous interpretation of the separate luminescent centers. Emergence of a narrow,Black/Brown Laminated New Film Faced / Marine Plywood Board Sheet/Panel for Doors/ Sales/ Boat.(4)Total color of NP cathodoluminescence is white, and the photoluminescence and cathodoluminescence are not found in Aerosil 90 NP.

Highlight

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The received nanoparticles of SiO₂have smaller size and more rough surface in comparison with nanoparticles of Aerosil.

The comparative analysis of magnetic, thermal,Factory Wholesale Price Metal Tinplate Lid for Glass Canning Jars.

The undoped SiO₂High Frequency Electric Induction Heating Welding Machine.

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Conflict of Interests

The authors declare that there is no conflict of interests regarding the publication of this paper.

Acknowledgments

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Copyright © 2015 Vladislav G. Il’ves et al. This is an open access article distributed under theHome Medical Rapid Temperature Measurement Handheld Vital Sign Monitor, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.