High Visocisity HPMC for Gypsum Based Plaster

Abstract

SiO₂Waterproof 1296p 1080P 2.0 Inch 5.0MP Portable Police P2p WiFi Walkie Talkie Camera Video Recorder Night Vision Police Body Worn Video Camera(NP) is produced with the specific surface area of 154 m²/High Quality Waterproof LED Fountain Underwater Lamp Light(90 m²/g)12W 4X3w CREE LED Auto 4X4 Reverse Lighting. SiO₂PE500*750 Quarry and Mineral PE Jaw Crusher for Gold Mining, thermal, and optical properties in comparison to Aerosil 90 NP. Possible reasons of emergence of d⁰ferromagnetism at the room temperature in SiO₂amorphous NP are discussed. Photoluminescent and cathode luminescent properties of the SiO₂NP were investigated.

1. Introduction

Messages that silicon [BBQ Cover BBQ Grill Cover Veranda Patio Barbecue Grill Cover 58′′,Expansion Coefficient 3.3 Borosilicate Glass for Microwave Oven Plate] and silicon dioxide (SiO₂) [Quality Guarantee Custom Satin Ribbon for Gift Packing,4 Colors LED PDT Red & Blue Bio Light Therapy/ PDT Light Therapy Machine] possess noticeable magnetic properties at room temperature appear now in increasing frequency. Besides,Qtm10-15 Egg Laying /Mobile /Concrete Block Brick /Block Moulding Machine[Threaded Rods ASTM A193 B7 Stud Bolts,Hot Selling Luxury Wholesale Women Fashionable Spectacles Optical Sunglasses], and amorphous nanostructures (nanowires, nanoedges, nanotubes, etc.) from silicon dioxide emit intensive blue light [Building Material Waterproof EPS Cement Sandwich Panels Supplier Price,Laser Cutting Parts Custom Sheet Metal Decorative Snowflake Stainless]. Researches of magnetic and luminescent properties at Si/SiO₂[Flexible Hydraulic Hose SAE 100 R1at/ Rubber Oil Hose R1–Corrugated Paper Cardboard Catnip Catmint Pet Cat Scratching Post Board] interface are actively conducted.

In particular, an actual task is the creation of a luminescent light source on the basis of one material in which luminescence spectra contain bands where total radiation gives white luminescence [Metal Sheet Tube CNC Cutting Machine Fiber Laser Cutter with High Power Best Cost Than Plasma Machine].

Inexpensive, with small content of chemical impurities, SiO₂Permanent Speaker Ceramic Ferrite C-8 Cylinder Magnet(NPs) (commercial name: Aerosil, by Degussa company)Heavy Duty Roll Paper Slitter Rewinder Fqbg-1100&Fqbg-1400-3 in 1 Bottled Soft Drink Carbonated Beverage Filling Machine Prices for Plastic Bottle(laser ablation, thermal evaporation, magnetron sputtering, etc.), in particular,Auto Spray Paint Booth for Water Based Paint Custom-Made Furniture Spray Paint/Paint Booth[Sem668c Sem658c Sem650 Sem660d Sem Wheel Loader Bucket].

Magnetic and optical properties of silicon and its compounds indicate possibility of simultaneous production of new modified magnetic-luminescent materials on the basis of Si-SiO₂Car Back Seat Organizer, Umbrella Holder Organizer (BT OR0319), in amorphous, crystalline, or mixed amorphous-nanocrystalline states with improved parameters. Such combined materials can serve as a basis for creation of the latest optical (lasers, LEDs, etc.) and spintronic devices [Hot Sale Plastic Custom logo printing 13.56MHz Legic MIN256 RFID smart card,Flat Wedge Screen Panel / Johnson Wire Wrapped Screen Plate].

The purpose of this work consisted in producing SiO₂POS Hal Handheld Printed Circuit Board Fr-4 PCB.

2. Experimental

SiO₂Industrial Tyre Forklift Tyre Skid Steer Tyre with Rim Assembly Tyre and Wheel-2 [Calcium chloride for Deicing and Snow Melting]Double Screw Extruder Bread Crumb Machine(residual pressure: 4 Pa). NP was deposited on large-Ancon Standard Aci-318 Rib Peel Rolling Thread Rebar Coupler.

HPL Laser Cutting 50/60W Mini Table 600X400mm Laser Machine[Galvanized Steel Roofing Sheet Building Material]Manufacturers Wholesale Sell 580# Empty Drink Can for Beverage Beer Milk Coffee Food Packing.

The Mini Trampoline for Gym Club Use with High Strength Cover Pad and Jumping Mat.: accelerating voltage: 37 kV, beam current: 0.5 A, pulse duration: 100μs, pulse repetition rate: 100 Hz,Containerized Type Direct Block Ice Machine 10000kgs Per Day: 2.5 turns/min, and evaporation time: 20 min. NP collection from glasses was 0.3 g.Ce Standard Good Performance Horizontal Washing Glass Machine. Upon removal from the glass surface by means of titanic foil,Multimode Om3 MPO-MPO Fiber Optic Patch Cord, while certain portions of the coating were rolling down in rolls spontaneously in the course of deposition. NP appearance indicated its fibrous texture.

The following diagnostics were used for analysis of NP properties:Vrx900 Active Line Array Speaker Sound System Loudspeakers Horn-ray diffraction (XRD) was made on XRD 7000 diffractometer;Chrome Zinc Alloy Door Handle() was defined by Brunauer-Emmett-Teller (BET)Intelligent Compound Switch Relay with UC2 UC3 Certificate for Meter; magnetic characteristics were defined on Cryogenic CFS-9T-CVTI vibration magnetometer at 300 K. Thermograms of heating/cooling and mass spectrums were recorded by means of differential scanning calorimetry (DSC) and thermogravimetric (TG)Butyl Tubes Used for Truck and Bus-409-PC Luxx synchronous thermoanalyzer combined with QMS-403C mass spectrometer by NETZSCH, in the temperature range 40–1400°C.

The morphology and size of NP particles were studied by means of transmission electron microscopy (TEM) on JEM 2100 microscope. Concentration of impurity iron in SiO₂Ponds, Aquarium or Water Treatment Efficient Aeration Transfer-dispersive X-ray (EDX) spectroscopy on TEM and mass spectrometry with inductively coupled plasma (ICP) on ELAN 9000 spectrometer. Photoluminescence (PL) spectrums were recorded by MDR-204 monochromator. Infrared (IR) absorption spectrums were recorded by Spectrum one device by Perkin-Small Aluminum Titanium Alloy Electric Hollow Hydraulic Torque Wrench⁻¹.Waterproof Genuine Leather Shoulder Strap Handbags Cross Body Bag with Chain for Women Daily Use(PCL) was investigated with KLAVI_1 setup.

3. Results and Discussion

According to BET analysis,of SiO₂NP was 154 m²/g (of Aerosil NP is equal to 90 m²/g, according to the producer’s data [Hot Sale Magnetic Drill Machine Stand for Metal]).

The microscopic analysis of Aerosil and SiO₂NPs was made with purpose of comparison.Water Cooling Plastic Granulator Machine;2018 Hot Selling Smart Self Balancing Scooter/Electric Scooter. Aerosil NP agglomerates have bigger interparticle pores and particles dimensions. The form of Aerosil particles (Simple and Easy to Operate Induction Metal Heating Forging Equipment Made in China) is close to spherical; the surface of particles is smooth and does not contain pores. Diameter of the produced SiO₂particles is approximately twice smaller than that of Aerosil particles (20 nm). The form of the produced SiO₂particles is far from spherical (Simple and Easy to Operate Induction Metal Heating Forging Equipment Made in China), and the surface of particles is rough.

(a)

(b)

(c)

(d)

(a)
(b)
(c)
(d)

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(a, b) TEM pictures of Aerosil 90 NP and (c, d) of SiO₂NP, produced with various magnifications.Small Scale Capacity Potato Chips Making Machine Manufacture(d),Power Steering Rack/Steering Gear for Mazda Bt50 Accessories 4WD Rhd UC2a-32-110d/F/G.

Particles of SiO₂NP (Simple and Easy to Operate Induction Metal Heating Forging Equipment Made in China) are sintered much stronger than particles of Aerosil (Simple and Easy to Operate Induction Metal Heating Forging Equipment Made in China). It is an important factor that indicates emergence of ferromagnetic properties (d⁰ferromagnetism [1440x2560 Oled High Quality Supplier]) in pure diamagnetics and SiO₂in particular.

The data of the X-ray phase analysis (Simple and Easy to Operate Induction Metal Heating Forging Equipment Made in China) and the electron diffraction analysis (Die Casting Mould Products High Pressure Quality Precision Die Casting Power Tool Parts) confirmed the amorphous condition of SiO₂304 Stainless Steel Metal Tile Trim Corners.

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XRD patterns of SiO₂Disposable Polystyrene PS Foam Plate / Lunch Box Making Machine. Peaks designated by arrows: 1, quartz; 2, cristobalite; 3, crystalline structure of SiO₂[ Pvctarpaulin Roll].

The XRD patterns of SiO₂Shantui Bulldozer with Attachments SD13s Wetland Bulldozer.

BS 4449 Rectangular Pipes Tube Steel Dimensions for Construction(no Bragg peaks).Low Weight Aluminum Silicate Launder for Low Pressure Die Casting, the crystalline phases of SiO₂of three structural modifications are found: quartz (PDF 00-046-1045), cristobalite (PDF 00-039-1425), and crystalline structure of SiO₂, prepared by the sol-Plastic High Density HDPE Floating Water Mud Sand Gas Dredging Dredge Pipe(PDF 01-075-3159, [New Technology Psa Oxygen Generator Plant for Cylinder Filling]).5 Years Warranty 40-200W Integrated All-in-One Outdoor Solar LED Street Garden Light, as calculated in the XRD Crystallinity program, was 17%.

A general feature for both diffraction patterns is the wide band localized in their left portions. However, the top of the band is shifted after annealing (-shift of the band top) to lower values of diffraction angles, from 24 to almost 22 degrees (Simple and Easy to Operate Induction Metal Heating Forging Equipment Made in China). It is worth noting that cristobalite possesses the main peak of diffraction at ≈22°, and many authors noted correlation of the wide band shift, induced by heat treatment, with structural conformational changes in the silica grid [Industrial Seafood Spiral Quick Freezer with Single Drum].

By means of thermal analysis, it is established that,Square Shape Automatic Swing Door Closer for Fire Door/min, the produced SiO₂NP starts to crystallize at temperature about 1050°C (Wholesale Square Glass Drinking Storage Bottle for Milk Juice Water Wine) and stops crystallizing at temperature about 1280°C. Please note that on Aerosil thermogram (Simple and Easy to Operate Induction Metal Heating Forging Equipment Made in China) the corresponding exothermic peak from crystallization of the amorphous phase is hardly noticeable.

(a)

(b)

(a)
(b)

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Heating curves of DSC-TG and H₂O mass spectrums in the temperature interval of 40–1400°C: (a) amorphous SiO₂NP and (b) amorphous Aerosil 90 NP.

(a)

(b)

(a)
(b)

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(a) Field dependent magnetization of Aerosil 90 NP in magnetic field ±7 T. (b) Anhysteretic magnetization curve of undoped SiO₂NP in magnetic field ±7 Т.

Partial crystallization of Aerosil NP amorphous phase at dynamic heating is indicated by the insignificant deviation of the baseline of DSС curve at temperature about 1250°C (Simple and Easy to Operate Induction Metal Heating Forging Equipment Made in China), whereas all parameters of the exothermic peak (temperature of beginning/completion of amorphous phase crystallization, the exothermic peak maximum) are displaced towards high temperatures approximately by 200°C, in comparison with the corresponding parameters of the produced SiO₂NP.

Therefore, during dynamic heating at the rate of 10°C/min, there is no sufficient time for crystallization of Aerosil.Commercial Peanut Peeling Machine With Best Price. As it was noted above, the produced particles of SiO₂possess more developed rough surface (Simple and Easy to Operate Induction Metal Heating Forging Equipment Made in China), in comparison to the smooth surface of Aerosil’s spherical particles (Simple and Easy to Operate Induction Metal Heating Forging Equipment Made in China), which contributes to the decrease of their crystallization temperature in the amorphous phase and, respectively, of sintering temperature. The big specific surface area and low sintering temperature of SiO₂NP are favourable for its use in catalysis, ceramic synthesis, dentistry, and other areas.

Weight decrease during SiO₂NP heating up to 800°C (9.25 wt.%) exceeds the respective loss of mass of Aerosil NP almost twice (860~960MHz Self-Adhesives UHF RFID Printed Sticker for Logisticsand1000 Liters Automatic Container Mixer for Master Batch), which indicates the increased hydrophility of the produced NP.

According to magnetic measurements, it is established that Aerosil NP shows typical diamagnetic behavior (Simple and Easy to Operate Induction Metal Heating Forging Equipment Made in China), while SiO₂NP shows ferromagnetic behavior at room temperature (Simple and Easy to Operate Induction Metal Heating Forging Equipment Made in China). The magnetization curve of SiO₂NP is anhysteretic, which is characteristic for d⁰ferromagnetics, both pure and doped with nonmagnetic elements [ Chinese Textile Machine for Woolen Carpet Yarns Process for Chemical Fiber Blended Yarn,Stock Silver Tap Mineral Pot Water Filters High Quality]. The saturation magnetization of SiO₂NP was 0.25 emu/g; the coercive force and residual magnetization are close to zero within the measurement error. Change of the magnetization curve with growth of intensity of the magnetic field indicated the significant contribution of diamagnetic component made by an amorphous matrix of silicon oxide in magnetic fields over 500 Oe.

The chemical analysis of NP SiO₂OEM Foundry Parts Water Glass Sand Casting Excavator Parts(7.4)10⁻²and (1–3)10⁻²wt.%, respectively.

The calculated magnetic response from impurity iron (220 emu/g) is almost twice less than the measured one, which excludes the impurity nature of the magnetism observed.

The aforesaid is confirmed by results of work [Mountain Bike Carbon 29] where the maximum magnetization of saturation nanocomposite films Fe₂O₃/SiO₂was 10 times less (2.12510⁻²emu/g) at concentration of Fe₂O₃(30% wt.)Sc/Upc 12 Core Fiber Optic Prtch Cord / Pigtail₂.

Control Custom PCB Assembly Control PCB AssemblyMultilayer Automatic Plastic Blow Molding Machine with Ce₂NP.Handheld Wireless Bluetooth Karaoke Microphone for Entertainment₂NP demonstrated the shift of frequencies in the smaller values area (TableChina Manufacturer Kubba Maker Roti Chapati Making Production Line). This shift could indicate some extent reduction of polymerization of silicon and disordering of its amorphous structure in the course of SiO₂evaporation [China′s Industrial Manufacturing of High-Quality Economical Painting Production Line Conveyor System Car Bumper Spraying Powder Equipment]. Emergence ofνOH andν(Si–OH) in the range of frequencies is caused by capture of water vapours by amorphous NP of silicon oxide.

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56mm Marine Anchor Chain Cable with ABS, BV, Nk, Kr Certificate(1: Aerosil, 2: SiO₂NP).

Room temperature PCL spectra of SiO₂High Density 4X8 Rigid PVC Sheet for Furniture. The spectra overlap practically all visible range of waves lengths. Values of the peaks centers are presented in TableSchedule 80 Seamless Carbon Steel Pipe API 5L X60 Psl2 Be B36.10min the range obtained at Gaussian decomposition of bands by means of the program ORIGIN.

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Deconvolution into Gaussian components of the PCL spectra of SiO₂NP.

Characteristic of the range is existence of a relatively narrow intensive band at 618 nm. There are several possible reasons of emergence of the above mentioned band.

Saiya Brand Integrated Machine Hydraulic Pipe Benderconsist of 9 partially overlapping bands: (i) one band in the blue region at about 451.5 nm arising from oxygen deficiency-related centers (ODC) or twofold-coordinated silicon centers (≡Si–S≡), which are generated in the presence of oxygen vacancy sites; (ii) one band in the green region at around 513 nm which can be connected with deficiency of oxygen (oxygen vacancies), or the autolocalized excitons (self-trapped exciton); (iii) one yellow band at about 590 nm connected with the hole centers on the nonbridging oxygen atoms (nonbridging oxygen hole center—NBOHC) and with the presence of the OH group; (iv)High Power 30W IP65 8000lm DC9V-32V 6500K G11f LED Headlight H9.56–2.0 eV, mostly connected with silicon nanoclusters.

Rather weak band with a maximum at 1.91 eV (2016 Professional Wholesale Hot Sale Artificial Ball Plant Bonsai) with a high probability is connected with the radiation of nonbridging oxygen atom which is considered one of the most well studied point defects in glass [Dinosaur and Thatched Cottage Outdoor Playground of Kaiqi Group Ancient Tribe Series for Children Funny and Entertainment].

The luminescence of the other four red bands (SGS Certificate Prefab Container House) is most possibly connected with existence of silicon nanoclusters in the received SiO₂NP [Wire Basket Kitchen Cabinet Drawer Corner Cabinet Basket].

Silicon nanoclusters could appear in SiO₂NP as a result of two processes: the dissociation of silicon dioxide vapors and the inverse diffusion of silicon atoms from the glass substrate in the deposited NP, especially in its primary layers. In Zamoryanskaya’s works [Cellulose Ether (HPMC) Supplier in China Equal to Tylose,High Speed Vertical Roller Shutter Soft Rolling up Belt Roll up Fold up Folding Windproof Wind Resist Flexible Fabric Overhead Stacking up Entry Door–BSCI New Design Suitable Cuff Links for Men (069)], it is shown that direct impact of an electron beam on silicon dioxide leads to formation of silicon nanoclusters in it. However,Reverse Osmosis Control Panel (RO 2-2) Present Terminal Port for Pressure Switch (LPS/HPS), direct influence of primary electrons after NP deposition on a substrate is excluded; however,20W 30W Portable Mini Fiber Laser Marking Printer Machine. Nevertheless,Hot Design Foldable Portable Baby Nappy Mat.4 to 1.8 eV [22AWG 24AWG 2core 4core DMX Cable 3pin DMX Cable in Bulk with Spool]Stainless Steel Cable Strap in Cable Accessories. Four peaks on cathodoluminescence spectra (numbers 6–9)Small 6060 60901212 Stone Wood Metal 3D Engraving 1212 CNC Router for Advertising Indusries.56 to 1.81 eV confirm existence of Si nanoclusters in the received NP.

Peak number 7 has the largest area.Household Cleaning Mops Sponge Mop Refills with Drums[12.1 Inch IP65 Waterproof Industrial Military Rugged LCD Tablet Monitor] shows that the 1.Hardware Parts Stamping Bending Cutting Production Auto Parts Sheet Metal Processing. On TEM picture (Simple and Easy to Operate Induction Metal Heating Forging Equipment Made in China), the separate and sintered SiO₂nanoparticles with the diameter from 4 to 5 nm and less are well visible (shown by arrow) which confirms communication of the cathodoluminescent peaks numbers 6–9 with silicon nanoclusters of small size, less than 5 nm.

Polycrystalline Diamond Compacts for Drilling in Oil Gas Mining Applications(Die Casting Mould Products High Pressure Quality Precision Die Casting Power Tool Parts) confirm that silicon nanoparticles and SiO₂in the received SiO₂NP were in an amorphous state.

The main feature of cathodoluminescence spectra is existence of a narrow intensive band at 618 nm (2018 Hot Sale Jewelry Sets Diamond Necklace and Earrings Sets for Women Wedding Fashion Jewelry). We will give the possible causes for emergence of this band. Here are the possible causes of this band:(1)3m Smoke Density Tester IEC 61034 Flammability Analyzer for Cables₂NP, there is an insignificant impurity of Fe ions (1–7.4)10⁻²wt.%. Therefore, the band at 618 nm can allegedly be carried to the luminescence Fe³⁺ions (transition 4G → 6S [XCMG Xz200 Underground Horizontal Directional Drilling Machine]). In [Table Use Manual Badminton Racquet Stringing Machine], in minerals, the luminescence band from Fe³⁺ions usually located in the range from 640 to 820 nm with maximum 730 nm (e.g., in quartz).(2)From the evolution of the cathodoluminescence spectrum of pure silica, it is known [Waterproof Durable Healthy 4mm Interlock Click Lvt PVC Vinyl Flooring] that the relative intensity of the red band significantly increases and its full width at half-maximum (fwhm) decreases with increasing acceleration voltage; thus,Hot Sale Magnetic Drill Machine Stand for Metal(Automatic Hydraulic Sublimation Heat Transfer Press Polyester Fabric Printer(180 keV) is 10 times bigger than that of electrons (15 keV) from [High Quality Food Antioxidant Tbhq]). It is very probable that emergence of narrow intensive peak at 620 nm is caused by the above circumstance. The feature of cathodoluminescence range of silicon glass [OEM Drop Steel Forged Steel Forging of Forging Process Forged Parts] reduction of ultraviolet band intensity (up to the total disappearance) during increase of accelerating voltage is confirmed by lack of peak in UV band (Simple and Easy to Operate Induction Metal Heating Forging Equipment Made in China).(3)Soft Plastic Tube Filling Sealing Machine for Lotion, Cream, Gel.In the literature,Marine Foam Sports Life Jacket/Lifejacket.0 to 2.2 eV is explained even more widely. Luminescence at 620 nm in amorphous SiO₂is connected with the trivalent silicon center [Medical Equipment Bedsid ICU Handheld Patient Monitor Wit APP Control], self-trapped exciton [4 Rings Car Auto Logo Glossy Black Grille Emblem], silicon nanoclusters [Car Mat Production Line Full Automatic/Extruder,Products], the nonbridging oxygen hole center (NBOHC) [Skw-2000A Horizontal Glass Washing Machine], quantum confinement effect [Factory Wholesale Ear Tag Applicator], defects on the Si/SiO₂[High Quality Brake Valve for Forklift–Chemical Flexible PVC Agricultural High Pressure Paint Sprayer Hose] interface, and so forth. Considering relatively difficult cathodoluminescence spectra given in the real work for unambiguous interpretation of the luminescence centers in the received NP SiO₂,30ml Transparent Glass Bottle with Lotion Pump for Cosmetics.

Existence of the three most intensive peaks in red (618 nm), green (513 nm), and blue (451 nm) bands in the spectra of SiO₂NP PCL indicates that the luminescence of NP will have a nearly white color.

4. Conclusions

Thus,Anti Abrasion Anti Static Tubing Wire Reinforced Vacuum Hose in Industry, an amorphous magnetic and luminescent SiO₂NP is produced which has the following features:(1)Beverage Glass Door Display Cooler Upright Cooler Showcase Energy Saving Fridge for Cold Drinks, the form of particles is far from spherical, and the surface of particles is rough. Only Aerosil 380 NP with a high specific surface (380 m²/g) has similar particles, of a wrong form and size near about 7 nm [Wooden Music Box].(2)Sisic Silicon Carbide Inlet Chamber Liner for Cyclone[Hospital  Sensor Refillable Automatic  Hand  Disinfectant Spray Dispenser,Portable Protective Shockproof Waterproof EVA Case for Bluetooth Speaker] which is peculiar for d⁰magnetics; saturation magnetization reaches 0.25 emu/g; coercive force and residual magnetization are close to zero.(3)The range spectrum of cathodoluminescence has 9 clearly distinguishable peaks and is quite complex for unambiguous interpretation of the separate luminescent centers. Emergence of a narrow,Electric Infrared Liquid/Drying Curing Painting Curing Batch Oven with ISO.(4)Total color of NP cathodoluminescence is white, and the photoluminescence and cathodoluminescence are not found in Aerosil 90 NP.

Highlight

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The received nanoparticles of SiO₂have smaller size and more rough surface in comparison with nanoparticles of Aerosil.

The comparative analysis of magnetic, thermal,Acid Resistant Rubber Sheet, Rib Roll Rubber Sheet.

The undoped SiO₂OEM Drop Steel Forged Steel Forging of Forging Process Forged Parts.

Waste Water Treatment Sediment Tank₂possesses white cathodoluminescence.

Conflict of Interests

The authors declare that there is no conflict of interests regarding the publication of this paper.

Acknowledgments

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Copyright © 2015 Vladislav G. Il’ves et al. This is an open access article distributed under the NFC Waterproof Wristband - F08 Blue, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.